WebSep 2, 2015 · Here we demonstrate how the hydrogen-bonding ability of a BINOL-based dialdehyde subcomponent dictated the stereochemical outcome of its subsequent self-assembly into one diastereomeric helicate ... WebOct 1, 2024 · Download : Download high-res image (69KB) Download : Download full-size image Luminescent chiral cocrystal based on the self-assembly of 2,2'-binaphthol and 2 …
Self-Assembly of Chiral Metallacycles and Metallacages from a …
WebSep 23, 2015 · Self-Assembly of Chiral Metallacycles and Metallacages from a Directionally Adaptable BINOL-Derived Donor Self-Assembly of Chiral Metallacycles and Metallacages from a Directionally Adaptable BINOL-Derived Donor J Am Chem Soc. doi: 10.1021/jacs.5b07529. Epub 2015 Sep 10. Authors WebSep 8, 2024 · The synthesis of unprecedented BINOL-derived cationic phosphonites is described. Through the use of these phosphanes as ancillary ligands in Au I catalysis, a highly regio- and enantioselective assembly of appropriately designed alkynes into 1-(aryl)benzo[5]carbohelicenes is achieved. The modular synthesis of these ligands and … dbs success profiles
The Influence of Different Spacer Lengths on the Selectivity of Self …
WebJun 14, 2024 · In this work, we demonstrate how the methylation of a subcomponent built around the 1,1′-bi-2-naphthol (BINOL) 15 moiety alters the stereochemical outcome of subcomponent self-assembly (Figure Figure1 1). 16,17 Methylation also changed the course of self-assembly within a system containing both a BINOL-based subcomponent … WebSep 9, 2024 · Condensation of an (S)- or (R)-BINOL-derived dialdehyde and tris(2-aminoethyl)amine produced chiral [2+3] imine cages, which were further reduced to furnish more stable chiral amine cages and applied in the enantioselective recognition of (1R,2R)- and (1S,2S … WebApr 13, 2024 · Novel materials from the supramolecular self-assembly of short helical ... Raja, S. & Rueping, M. Complete field guide to asymmetric BINOL-phosphate derived Brønsted acid and metal catalysis ... ged evening classes